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New Zn complexes based on 1,2,4-triazoles: Synthesis, structure and luminescence |
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| Authors: | Alexey N Gusev Victor F Shul’gin Svetlana B Meshkova Mikhail A Kiskin Wolfgang Linert |
| Institution: | a Taurida National V.I. Vernadsky University, Simferopol 95007, Ukraine b A.V. Bogatsky Physico-Chemical Institute of the National Academy of Sciences of Ukraine, Odessa 65080, Ukraine c N.S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Moscow 119991, Russia d Institute for Applied Synthetic Chemistry, Vienna University of Technology, Getreidemarkt 9/163, A-1060 Vienna, Austria |
| Abstract: | The reaction of 3-(pyridin-2-yl)-5-(2-aminophenyl)-1H-1,2,4-triazole and salicylaldehyde or benzaldehyde leads a new type of 1,2,4-triazole’s derivats. Reactions of these ligands with zinc acetate in ethanol lead to the formation of two new complexes with azomethine or dihydrotriazaindolizine form of ligands. The structures of these complexes were investigated by X-ray analysis. The complexes showed strong green-blue luminescence in solid state. |
| Keywords: | 1 2 4-Triazole Zinc complexes X-ray study Luminescence |
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