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Coordination network solids based on Cu(II) coordination compounds with 1,4-bis-(1,2,4-triazol-1-yl)-butane as a flexible alkyl spacer ligand: Synthesis, characterization and X-ray structures |
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| Authors: | Peerke I.M. van der List Elza N. Lugthart Patrick Gamez Jaap G. Haasnoot Olivier Roubeau Jan Reedijk |
| Affiliation: | a Leiden Institute of Chemistry, Leiden University, P.O. Box 9502, 2300 RA Leiden, The Netherlands b Advanced Light Source, Berkeley Lab, 1 Cyclotron Road, Berkeley, CA 94720, USA c ICREA, Universitat de Barcelona, Departament de Química Inorgànica, Barcelona, Spain d Instituto de Ciencia de Materiales de Aragón, CSIC and Universidad de Zaragoza, Plaza San Francisco, s/n 50009 Zaragoza, Spain e Laboratory of Inorganic Chemistry, Department of Chemistry, P.O. Box 55, A.I. Virtasenaukio 1, University of Helsinki, Helsinki 00014, Finland f Department of Chemistry, King Saud University, P.O. Box 2455, Riyadh 11451, Saudi Arabia |
| Abstract: | The coordination chemistry of three selected copper(II) salts with the flexible ligand 1,4-bis(1,2,4-triazol-1-yl)butane (abbreviated as btb) is described. This ligand acts as a bidentate ligand, bridging copper(II) ions, thereby generating polymers in 2D and 3D network solids. |
| Keywords: | Copper(II) Flexible spacer Crystal structure Framework Coordination polymers |
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