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Copper(II) assisted hydrolysis of 2,4,6-tris(pyrazol-1-yl)-1,3,5-triazine. Crystal and molecular structure of catena-[CuL(H2O)Cl]n (L = 2,4-dione-1,3,5-(1H)-triazin-1-amido) |
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| Authors: | Jorge Manzur,Carolina Acuñ a,Ana Marí a Garcí a |
| Affiliation: | a Facultad de Ciencias Físicas y Matemáticas, Universidad de Chile, Departamento de Ciencia de los Materiales, Tupper 2069, Santiago, Chile b Universidad Andres Bello, Facultad de Ecología y Recursos Naturales, Departamento de Ciencias Químicas, República 275, Santiago, Chile c Centro para en Desarrollo de la Nanociencia y la Nanotecnología, CEDENNA, Chile |
| Abstract: | This article describes the partial hydrolysis of the multidentate ligand 2,4,6-tris(pyrazol-1-yl)-1,3,5-triazine in the presence of copper(II), to give the anionic ligand 2,4-dione-1,3,5-(1H)-triazin-1-amido, which was isolated as the cupric complex catena-[CuL(H2O)Cl]n, where L is the amido ligand. No other hydrolysis products were isolated or identified.The complex defines a zigzag 1D covalent chain, along the b cell axis, through apical copper-oxygen bonds (Cu-N-C-O···Cu bridges). |
| Keywords: | Copper complex Hydrolysis 1,3,5-Triazine Molecular structure |
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