The synthesis and cyclic voltammetry of select ferrocene piano-stool isocyanide complexes |
| |
| Authors: | Brian D. Humphrey Raidiri E. Castilo Argelia Feliciano |
| |
| Affiliation: | a Department of Chemistry and Biochemistry, Montclair State University, Upper Montclair, NJ 07043, USA
b Department of Natural Sciences, Felician College, Lodi, NJ 07644, USA |
| |
| Abstract: | Ferrocene piano-stool isocyanide complexes ([CpFeL3]+, Cp = η5-C5H5, L = tert-butyl isocyanide (1), cyclohexyl isocyanide (2), and 2,6-dimethylphenyl isocyanide (3)) are formed by chemical oxidation of ferrocene in the presence of a stoichiometric amount of isocyanide ligand (1:3). The complexes are characterized by elemental analysis, routine spectroscopic methods (IR, 1H NMR, 13C NMR, and UV-Vis), and cyclic voltammetry. |
| |
| Keywords: | Ferrocene piano-stool complex Isocyanide ligand Cyclic voltammetry Organometallic chemistry |
| 本文献已被 ScienceDirect 等数据库收录！ |
|
