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Simple physical presentation of enzymatic catalysis
Authors:M.K. Volkenstein
Affiliation:Institute of Molecular Biology, Academy of Sciences of the U.S.S.R., Moscow, U.S.S.R.
Abstract:The electronic-conformational interactions (ECI) in enzyme-substrate complexes are illustrated by an elementary model of electron oscillating in a parabolic potential box. The decrease in activation energy for the elementary act of enzymatic reaction is due to ECI-to increased pressure at the walls of the box produced by excited electron.
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