Synthesis of racemic 9-methyl-10-hexadecenoic acid |
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Authors: | Carballeira N M Sostre A Restituyo J A |
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Affiliation: | Department of Chemistry, University of Puerto Rico, San Juan 00931-3346. ncarball@upracd.upr.clu.edu |
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Abstract: | The marine bacterial fatty acid 9-methyl-10-hexadecenoic acid was conveniently prepared in 6 steps and in a 22% overall yield, starting from commercially available methyl 10-hydroxydecanoate. The naturally occurring fatty acid has the E double bond configuration as confirmed by gas chromatographic co-elution experiments. |
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