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Structure of sterically hindered aryl derivatives of five-membered nitrogen containing heterocyclicortho-analogs of POPOP
Authors:A O Doroshenko  L D Patsenker  V N Baumer  L V Chepeleva  A V Van'Kevich  A V Kirichenko  S N Yarmolenko  V M Scherschukov  V G Mitina  O A Ponomaryov
Institution:(1) Institute for Chemistry at Kharkov State University, 4 Svobody Square, 310077 Kharkov, Ukraine;(2) Institute for Single Crystals, Ukrainian Academy of Sciences, 60 Lenin Avenue, 310001 Kharkov, GSP, Ukraine
Abstract:The molecular conformation of three newly synthesized, sterically hindered aryl derivatives of five-membered nitrogen-containing heterocyclicortho-analogs of POPOP were studied by X-ray analysis and vibrational spectroscopy. It was shown that molecules of the compounds in the crystalline state and in solution are non-planar and asymmetric.
Keywords:X-ray analysis  vibrational spectroscopy  conformation analysis  1  4-bis-(5-phenyloxazolyl-2)-benzene (POPOP) analogs
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