(1) Institute for Chemistry at Kharkov State University, 4 Svobody Square, 310077 Kharkov, Ukraine;(2) Institute for Single Crystals, Ukrainian Academy of Sciences, 60 Lenin Avenue, 310001 Kharkov, GSP, Ukraine
Abstract:
The molecular conformation of three newly synthesized, sterically hindered aryl derivatives of five-membered nitrogen-containing heterocyclicortho-analogs of POPOP were studied by X-ray analysis and vibrational spectroscopy. It was shown that molecules of the compounds in the crystalline state and in solution are non-planar and asymmetric.