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Unexpected synthesis and structural characterization of Pt(II)Cl2-1,5-hexadiene from reaction of allyl chloride and K2PtCl4 |
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| Authors: | Reji N Nair Arnold L Rheingold |
| Institution: | a Department of Chemistry and Biochemistry, 5500 Campanile Drive, San Diego State University, San Diego, CA 92182-1030, United States b Department of Chemistry and Biochemistry, University of California, San Diego, La Jolla, CA 92093-0358, United States c Department of Chemistry and Biochemistry, University of Massachusetts Dartmouth, North Dartmouth, MA 02747, United States |
| Abstract: | An unexpected, new and convenient synthetic procedure for the synthesis of Pt(II)Cl2-1,5-hexadiene is reported which is done under mild conditions, including a very short reaction time of 10 min. The complex was isolated and crystallized, leading to the first reported crystal structure of the diene complex. |
| Keywords: | Platinum complexes X-ray crystal structures Allyl Diene |
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