Mononuclear single helices of lanthanum(III) and europium(III). Metal dependent diastereomeric excess |
| |
Authors: | Senjuti De Dipankar Datta |
| |
Institution: | a Department of Inorganic Chemistry, Indian Association for the Cultivation of Science, Calcutta 700 032, India b School of Chemistry, The University, Whiteknights, Reading RG6 6AD, UK |
| |
Abstract: | Using the 1:2 condensate of benzildihydrazone and 2-acetylpyridine as a tetradentate N donor ligand L, LaL(NO3)3 (1) and EuL(NO3)3 (2), which are pale yellow in colour, are synthesized. While single crystals of 1 could not be obtained, 2 crystallises as a monodichloromethane solvate, 2·CH2Cl2 in the space group Cc with a = 11.7099(5) Å, b = 16.4872(5) Å, c = 17.9224(6) Å and β = 104.048(4)°. From the X-ray crystal structure, 2 is found to be a rare example of monohelical complex of Eu(III). Complex 1 is diamagnetic. The magnetic moment of 2 at room temperature is 3.32 BM. Comparing the FT-IR spectra of 1 and 2, it is concluded that 1 also is a mononuclear single helix. 1H NMR reveals that both 1 and 2 are mixtures of two diastereomers. In the case of the La(III) complex (1), the diastereomeric excess is only 10% but in the Eu(III) complex 2 it is 80%. The occurrence of diastereomerism is explained by the chiralities of the helical motif and the type of pentakis chelates present in 1 and 2. |
| |
Keywords: | Lanthanum(III) Europium(III) Helicates Diastereomer Diastereomeric excess |
本文献已被 ScienceDirect 等数据库收录! |
|