Facile synthesis of benzyl beta-D-galactofuranoside. A convenient intermediate for the synthesis of D-galactofuranose-containing molecules |
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| Authors: | Mariño Karina Baldoni Luciana Marino Carla |
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| Institution: | CIHIDECAR (CONICET), Departamento de Química Orgánica, Facultad de Ciencias Exactas y Naturales, Universidad de Buenos Aires, Pabellón II, Ciudad Universitaria, 1428 Buenos Aires, Argentina. |
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| Abstract: | Benzyl beta-D-galactofuranoside was efficiently obtained from 1,2,3,5,6-penta-O-benzoyl-alpha,beta-D-galactofuranose, via benzyl 2,3,5,6-tetra-O-benzoyl-beta-D-galactofuranoside. Conditions for the O-debenzylation were investigated in order to evaluate the synthetic application of the benzyl group as an anomeric protector of a galactofuranose moiety in synthetic strategies involving galactofuranose. |
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| Keywords: | d-Galactofuranosides" target="_blank">β-d-Galactofuranosides Benzyl galactofuranoside d-Galactofuranosidase substrate" target="_blank">exo-β-d-Galactofuranosidase substrate Raney nickel |
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