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Interconversion and disproportionation reaction among cyclodextrin homologues in an aqueous two-phase-forming solution
Authors:Woo-Jin Chang  Yoon-Mo Koo
Affiliation:(1) Department of Biological Engineering, Inha University, Inchon, 402-751, Korea
Abstract:Interconversion reactions of cyclodextrin glycosyltransferase (CGTase) among cyclodextrin (CD) homologues were experimentally investigated using each CD as a substrate in an aqueous, two-phase-forming polymer solution of dextran and polyethylene glycol. Degradation rate of agr-CD was highest and that of beta-CD was lowest among agr-, beta- and gamma-CD with Bacillus macerans CGTase. Degradation of each CD was accelerated with dextran, while decelerated with polyethylene glycol.
Keywords:cyclodextrin glycosyltransferase  effect of polymers  interconversion reaction
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