1.Department of Chemistry,University of Saida—Docteur Moulay Tahar,Saida,Algeria
Abstract:
In this work we studied the structural and electronic properties of the metal–Schiff base complexes Ni( {mathrm{L}}_2^2 ) (1), Pd( {mathrm{L}}_2^1 ) (2), Zn( {mathrm{L}}_2^2 ) (3), and Ni( {mathrm{L}}_2^1 )(4), where L1 and L2 are Schiff bases synthesized from salicylaldehyde and 2-hydroxy-5-methylbenzaldehyde, respectively. Natural bond analysis showed that in complexes 1 and 2, the metal ion coordinates to the ligands through electron donation from lone pairs on ligand nitrogen and oxygen atoms to s and d orbitals on the metal ion. In complex 3, metal–N and metal–O bonds are formed through charge transfer from the lone pairs on nitrogen and oxygen atoms to an s orbital of Zn. Dimethylation of the phenolate rings in the ligands decreases the energy gap and redshifts the spectrum of the nickel complex. The main absorptions observed were assigned on the basis of singlet-state transitions. The simulated spectra of the two complexes 1 and 2 are characterized by excited states with ligand-to-ligand charge-transfer (LLCT), metal-to-ligand charge-transfer (MLCT), ligand-to-metal charge-transfer (LMCT), and metal-centered (MC) character.
