Ketoisophorone transformation by Marchantia polymorpha and Nicotiana tabacum cultured cells |
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| Authors: | Hegazy Mohamed-Elamir F Hirata Toshifumi Abdel-Lateff Ahmed el-Razek Mohamed H Abd Mohamed Abou El-Hamd H Hassan Nahed M Paré Paul W Mahmoud Ahmed A |
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| Affiliation: | Chemistry of Medicinal Plants Department, National Research Centre, Dokki, Cairo, Egypt. elamir77@yahoo.com |
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| Abstract: | Stereospecific olefin (C=C) and carbonyl (C=O) reduction of the readily available prochiral compound ketoisophorone (2,2,6-trimethyl-2-cyclohexene-1,4-dione) (1) by Marchantia polymorpha and Nicotiana tabacum cell suspension cultures produce the chiral products (6R)-levodione (2), (4R,5S)-4-hydroxy-3,3,5-trimethylcyclohexanone (3), and (4R,6R)-actinol (4) as well as the minor components (4R)-hydroxyisophorone (5) and (4S)-phorenol (6). |
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