Photoinduced interaction of riboflavin dye with different reducing agents in aqueous and liposome media |
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Authors: | Bhowmik Benoy B Sil Arpita |
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Institution: | Department of Chemistry, Centre for Surface Science, Jadavpur University, Kolkata 700 032, India. bhowmikbbju@yahoo.co.in |
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Abstract: | The photoelectrochemical and spectral studies of riboflavin have been carried out in aqueous and phosphatidylcholine (PC) liposome media in presence of different reducing agents such as I-, Br-, Cl-, Fe2+, Fe(CN)6(4-) and Cu+. The results from both the studies support the photoinduced electron transfer from the reducing agent to the excited riboflavin dye. Moreover, a good correlation between photovoltages/Stern-Volmer quenching constants versus reduction potentials of the reducing agents also confirms the above electron transfer in the photoexcited state. An alternative method has been developed to determine the Stern-Volmer quenching constant. |
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Keywords: | Riboflavin Stern-Volmer quenching constant Photoelectrochemical studies PC liposome Photovoltage |
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