Crystal structure and nuclease activity of mono(1,10-phenanthroline) copper complex |
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Authors: | Lu Li-Ping Zhu Miao-Li Yang Pin |
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Institution: | Institute of Molecular Science, Shanxi University, Taiyuan, China. |
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Abstract: | The hydroxo-bridged dinuclear copper (II)/phen complex Cu(2)(phen)(2)(OH)(2)(H(2)O)(2)]Cu(2)(phen)(2)(OH)(2)Cl(2)]Cl(2).6H(2)O (phen=1,10-phenanthroline) has been prepared and characterized by single crystal X-ray diffraction. The coordinated area of the complex shows two distorted CuN(2)O(2)O(w)] and CuN(2)O(2)Cl] square-pyramidal and one strictly planar configuration CuO(2)Cu involving two O atoms of hydroxo-bridged, Cu(2+) cations, N atoms of two phen ligands and disorder solvate water and chlorine anions. In the presence of H(2)O(2), the complex of mono(1,10-phenanthroline)copper exhibits higher activity as a nuclease than bis(1,10-phenanthroline)copper. |
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