Distribution of acetylenic thiophenes in the pectidinae |
| |
Authors: | K.R. Downum D.J. Keil E. Rodriguez |
| |
Affiliation: | 1. Phytochemical Laboratory, Department of Ecology and Evolutionary Biology, University of California, Irvine, CA 92717, U.S.A.;2. Department of Biological Sciences, California Polytechnic State University, San Luis Obispo, CA 93407, U.S.A. |
| |
Abstract: | The distribution and quantitative significance of biosynthetically related di- and ter-thiophenes from 27 species representing seven genera of the Pectidinae (Heliantheae) was investigated by reverse-phase HPLC. Adenophyllum, Chrysactinia and Nicolletia, three previously unstudied genera, were found to contain thiophenes for the first time. Four derivatives, 5-(4-hydroxy-1-butenyl)-2,2′-bithiophene (1), 5-(4-acetoxy-1-butenyl)-2,2′-bithiophene (2), 5-(3-buten-1-ynyl)-2,2′-bithiophene (3) and 2,2′:5′,2″-terthiophene (4) were common constituents in most species of Adenophyllum, Chrysactinia, Dyssodia, Hymenatherum, Nicolletia and Porophyllum. One additional compound, 5-methyl-2,2′:5′,2″-terthiophene (5), was also present in extracts of Adenophyllum, Dyssodia and Hymenatherum, but was not detected in any other genus. Acetylenic thiophenes were not found in any of the 18 species of Pectis examined. |
| |
Keywords: | Pectidinae Asteraceae distribution of acetylenic thiophenes |
本文献已被 ScienceDirect 等数据库收录! |
|