FeIII(SR)4]1- complexes can be synthesized by the direct reaction of thiolates with FeCl3 |
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| Authors: | Chang Sechin Koch Stephen A |
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| Affiliation: | Department of Chemistry, State University of New York at Stony Brook, Stony Brook, NY 11794-3400, USA. |
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| Abstract: | It is shown that the previously characterized [Fe(III)(SR)(4)](1-) (R=Et, i-Pr, Ph) complexes can be synthesized by the direct reaction of 4equiv. of LiSR with FeCl(3) in DMF solution. [Fe(III)(SR)(4)](1-) complexes are synthetic analogs for the [Fe(III)(S-Cys)(4)] center in rubredoxin proteins. |
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