An unusual bowl-shaped aluminum-nitrogen cage compound |
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| Authors: | Piyush Shukla Alan H. Cowley Jamie N. Jones |
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| Affiliation: | a Department of Chemistry and Biochemistry, University of Texas at Austin, Austin, TX 78712, USA
b Chemistry Division, Los Alamos National Laboratory, MS J514, Los Alamos, NM 87545, USA |
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| Abstract: | Trimethylaluminum reacts with 2,6-diaminopyridine in a 3:2 mole ratio to form the unusual cage-type compound AlMe[AlMe2{N(H),N(H)-C5H3N}]2 (1). The structure of 1, which was established by single crystal X-ray diffraction, features an overall bowl shape. The bowls stack along the (0 1 0) direction. |
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| Keywords: | Aluminum Nitrogen Cage Crystal structure |
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