Bond valence sums and structural studies of antimony complexes containing Sb bonded only to O ligands |
| |
Authors: | Ruth C. Palenik |
| |
Affiliation: | Chemistry Department, The University of Florida, P.O. Box 117200, Gainesville, FL 32611-7200, USA |
| |
Abstract: | New R0 values for Sb(III)-O of 1.955(13) Å and for Sb(V)-O of 1.912(12) Å were derived from a bond valence sum, or BVS, analysis of of 123 SbOn fragments with n = 3-7. These R0 values can be used to calculate the oxidation state, or OS, of Sb in complexes where Sb is bonded only to O ligands. If the OS of the Sb ion is uncertain, the average R0 value of 1.934 Å can be used to decide between the +3 or +5 OS from the observed Sb-O bond distances without any assumptions. The Sb-O distances used in deriving the R0 values for the +3 and +5 complexes are tabulated as a function of coordination number and have a wide range of values, but the average Sb-O distance reflects the requirement that the BVS must equal the OS. To supplement the Sb-O data, 2 new antimony tartrates were synthesized, and their crystal structures were determined. A single crystal structure determination of NaSb(OH)6, an unexpected reaction product, gave Sb-O distances that were also included in our BVS analysis. |
| |
Keywords: | Antimony complex Bond valence sums Crystal structures Tartrates Antimony-oxygen distances |
本文献已被 ScienceDirect 等数据库收录! |
|