Insertion reactions of organic anhydrides into the Cu-O bond of [CuOBu]: syntheses and structures of functionalised copper (I) and copper (II) carboxylates |
| |
| Authors: | Lukasz Ponikiewski |
| |
| Affiliation: | Institut für Anorganische Chemie, Universität Karlsruhe, Engesserstraße 15, D-76131 Karlsruhe, Germany |
| |
| Abstract: | The insertion reaction of maleic anhydride into the Cu-O bond in [CuOtBu] produced the complexes [Cu2(CO2C2H2CO2tBu)4 · dme] (1), [Cu(CO2C2H2CO2tBu)2 · tmeda] (2) and [Cu2(CO2C2H2CO2tBu)2 · dppm]2 (3) (dme = 1,2-dimethoxyethane; tmeda = N1,N1,N2,N2-tetramethylethane-1,2-diamine; dppm = bis(diphenylphosphino)methane). This reaction represents a useful synthetic strategy for a range of functionalised Cu(I) and Cu(II) carboxylates. |
| |
| Keywords: | Copper (I)alkoxide Organic anhydride Insertion reactions Crystal structures Copper carboxylates |
| 本文献已被 ScienceDirect 等数据库收录！ |
|
