Synthesis, chemical- and electrochemical properties of ruthenium(II) complexes bearing 2,6-bis(2-naphthyridyl)pyridine |
| |
| Authors: | Take-aki Koizumi |
| |
| Institution: | Coordination Chemistry Laboratories, Institute for Molecular Science and CREST, Japan Science and Technology Agency (JST), 5-1 Higashiyama, Myodaiji, Okazaki, Aichi 444-8787, Japan |
| |
| Abstract: | Ruthenium complexes with a terpyridine-analogous ligand, 2,6-bis(2-naphthyridyl)pyridine (bnp), have been synthesized and their chemical and electrochemical properties investigated. The structures of Ru(bnp)(tpy)](PF6)2 (1) and Ru(bnp)2](PF6)2 (2) were determined by the X-ray structure analysis. The bnp localized redox potentials of 1 and 2 showed significant positive shift by 260-290 mV relative to the analogous Ru-terpyridine complexes. |
| |
| Keywords: | Ruthenium Crystal structures Electrochemistry Cyclic voltammetry |
| 本文献已被 ScienceDirect 等数据库收录！ |
|
