Synthesis and characterization of [Ru(NO)(bpp)Cl · 2H2O] [bpp = N,N′-bis(2-pyridinecarboxamide)-1,3-propane dianion] and [Ru(NO)(bpe)Cl · 2H2O] [bpe = N,N′-bis(2-pyridinecarboxamide)-1,2-ethane dianion] |
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| Authors: | Carol F. Fortney Steven J. Geib Fu-tyan Lin Rex E. Shepherd |
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| Affiliation: | Department of Chemistry, University of Pittsburgh, Pittsburgh, PA 15260, USA |
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| Abstract: | Two ruthenium nitrosyl bis-pyridyl/biscarboxamido compounds, [Ru(NO)(bpp)Cl · 2H2O] [bpp = N,N′-bis(2-pyridinecarboxamide)-1,3-propane dianion] and [Ru(NO)(bpe)Cl · 2H2O] [bpe = N,N′-(bis-2-pyridinecarboxamide)-1,2-ethane dianion] have been characterized by 1H NMR, 13C{1H} NMR, and IR spectroscopies, electrospray ionizaton mass spectrometry, and X-ray crystallography. |
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| Keywords: | Carboxamido ligands {RuNO}6 Ruthenium nitrosyl Linear nitrosyl Split NO |
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