A novel one-dimensional acentric copper(I) coordination polymer with second-harmonic generation response |
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| Authors: | Xue-Feng Huang |
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| Institution: | Coordination Chemistry Institute, The State Laboratory of Coordination Chemistry, Nanjing University, Nanjing 210093, PR China |
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| Abstract: | The reaction of N,N-(2-pyridyl)(4-pyridylmethyl)amine with Cu(MeCN)2(PPh3)2]ClO4 in the presence of THF affords a novel one-dimensional copper(I) coordination polymer {Cu(PPh3)(N,N-(2-pyridyl)(4-pyridylmethyl)amine)](ClO4)}n (1), which crystallizes in an noncentrosymmetric space group and displays strong second-harmonic generation (SHG) response. |
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| Keywords: | Acentric Second-harmonic generation response Copper(I) coordination polymer |
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