Glechomanolides and eudesmanolides from Smyrnium perfoliatum |
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| Institution: | 1. United States Department of Agriculture, Agricultural Research Service, 10300 Baltimore Avenue, Beltsville, MD, 20705-2325, USA;2. Department of Chemistry and Biochemistry, University of Maryland, College Park, MD, 20742, USA;3. Department of Mechanical Engineering, University of Maryland Baltimore County, Catonsville, MD, 21250, USA;1. Pharmazeutisches Institut, Abteilung Pharmazeutische Biologie, Christian-Albrechts-Universität zu Kiel, Gutenbergstraße 76, 24118 Kiel, Germany;2. Dipartimento di Farmacia, Università di Napoli Federico II, Via Domenico Montesano 49, 80131 Napoli, Italy;1. School of Traditional Chinese Medicine, Guangdong Pharmaceutical University, Guangzhou, China;2. Department of Natural Product Chemistry, School of Pharmacy, Second Military Medical University, Shanghai, China;3. Department of Pharmacy, Shanghai Institute of Pharmaceutical Industry, Shanghai, China;4. Laboratory of Pharmaceutical Resource Discovery, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian, China |
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| Abstract: | In addition to five known sesquiterpenoids, six new compounds were isolated from Smyrnium perfoliatum. The new compounds were 1β-acetoxy-eudesma-3,7(11),8-trien-8,12-olide, 1β-acetoxyeudesma-4(15),7(11),8-trien-8,12-olide, 1β-10α;4α,5β-diepoxy-8β-isobutoxy-glechomanolide, 1β, 10α;4α,5β-diepoxy-8α-isobutoxy-glechomanolide, 1β,4α-dihydroxy-2α,3α-epoxy-eudesma-7(11),8-dien-8,12-olide, 1β,4α-dihydroxy-2α,3α-epoxy-8β-methoxy-eudesma-7(11)-en-8α,12-olide. |
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