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Picosecond geminate recombination of nitrosylmyoglobins
Authors:K A Jongeward  J C Marsters  M J Mitchell  D Magde  V S Sharma
Abstract:The kinetics of NO geminate recombination to sperm whale and elephant myoglobins has been studied on the picosecond time scale using an amplified colliding-pulse mode-locked ring dye laser. The dynamics of ligand rebinding are shown to be affected by the distal structure of the protein surrounding the heme pocket.
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