The electrochemistry of a surface modified, cationic, tetra-(N-methyl)pyridiniumporphyrazinocopper electrode |
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Authors: | Minghui Qi |
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Institution: | Department of Chemistry, York University, CB124, 4700 Keele Street, Toronto, Ontario, Canada M3J 1P3 |
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Abstract: | The surface electrochemistry of a graphite electrode surface modified with cationic, tetra-(N-methyl)pyridiniumporphyrazinocopper is reported. The surface deposited species is spontaneously reduced by one electron by the electron rich graphite surface. Several concerted two-electron processes are recorded. A Pourbaix diagram is used to display the various species that can be identified on the surface with change of electrode polarization and pH of the electrolyte. |
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Keywords: | Porphyrazine Electrochemistry Pourbaix diagrams Copper Cationic Surface modified |
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