Square-planar and trigonal prismatic silver(I) in bipyrimidine and oxalate bridged tetranuclear complexes and one-dimensional compounds: Synthesis and crystal structures

The reaction of Ag₄(hfac)₄(THF)₂] (hfac⁻ = 1,1,1,5,5,5-hexafluoroacetylacetonate, THF = tetrahydrofurrane) with 2,2′-bipyrimidine (bpm) leads to single crystals. They crystallise in the triclinic system, space group . Their structure consists of Ag₄(hfac)₄(μ₂-bpm)₃] tetranuclear complexes. In this complex, Ag(I) ions adopt distorted square planar and trigonal prismatic geometries. When Ag₄(hfac)₄(THF)₂] is replaced by monohydrated silver(I) perchlorate, a one-dimensional (1D) compound with a formula of Ag(μ₂-bpm)]⁺]_n, is obtained as single crystals. They crystallise in the monoclinic system, space group P2₁/c. Their structure consists of Ag(μ₂-bpm)]⁺]_n chains separated by non-coordinated perchlorate ions. In the chains, the Ag(I) centres adopt a square planar geometry. Finally, starting from Ag(μ₂-bpm)]⁺]_n, and sodium oxalate , another 1D compound with a formula of Ag(μ₂-bpm)(μ₂-ox)]_n, 4nH₂O is obtained as single crystals. They crystallise in the triclinic system, space group . In these chains, bipyrimidine and oxalate are alternate. They generate a square planar geometry around the Ag(I) cations.