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Syntheses of naturally occurring terphenyls and related compounds |
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| Authors: | Sawayama Yusuke Tsujimoto Takashi Sugino Kumi Nishikawa Toshio Isobe Minoru Kawagishi Hirokazu |
| Affiliation: | Graduate School of Bioagricultural Sciences, Nagoya University. |
| Abstract: | Naturally occurring terphenyls and related compounds such as terferol and its corresponding quinone and phlebiarubrone were synthesized from 2,5-diphenyl-1,4-benzoquinone. According to the proposed biosynthetic pathway, chemical conversion of phlebiarubrone to ustalic acid, a toxic compound isolated from the poisonous mushroom, Tricholoma ustale, was examined to find a low-yield conversion to the ustalic acid dimethyl ester. |
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