Synthesis of mixed ligand cationic rhodium(I) complexes with diolefin and substituted quinoline N-oxides as ligands |
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| Institution: | 1. Institute of Applied Chemistry, Shanxi University, Taiyuan 030006, China;2. Key Laboratory of Engineering Plastics and Beijing National Laboratory for Molecular Science, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China;3. The School of Chemistry and Chemical Engineering, Shanxi University, Taiyuan 030006, China;4. Department of Chemistry, University of Leicester, University Road, Leicester LE1 7RH, UK;5. CAS Research/Education Center for Excellence in Molecular Sciences, University of Chinese Academy of Sciences, Beijing 100049, China;1. Chair of Forest Biomaterials, University of Freiburg, Werthmannstr. 6, 79085 Freiburg, Germany;2. Freiburg Materials Research Center, University of Freiburg, Stefan-Meier-Str. 21, 79104 Freiburg, Germany;3. Institute of Inorganic and Analytical Chemistry, University of Freiburg, Albertstr. 21, 79104 Freiburg, Germany;1. Postgraduate Department of Chemistry, Panskura Banamali College, Panskura RS, WB 721152, India;2. Department of Chemistry, CICECO-Aveiro Institute of Materials, University of Aveiro, 3810-193 Aveiro, Portugal |
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| Abstract: | The mixed ligand cationic rhodium(I) complexes of the type Rh(COD)LL′]C104 (L=QNO, 2-Me- QNO, 4-MeQNO, 4-C1QNO, 2-PhQNO; L′=4-NH2py, 4-NMe2py, Im, PPh3) have been prepared and characterized. The reactions of Rh(COD)(4-MeQNO)2]- C104 with various ligands are also reported. |
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