Ruthenium(II) complexes derived from 2-(methylamino)pyridine |
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| Affiliation: | 1. College of Mechanical and Electrical Engineering, Northeast Forestry University, Harbin 150040, China;2. Wuhan Maritime Communication Research Institute (WMCRI), Wuhan 430205, China |
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| Abstract: | 2-(Methylamino)pyridine reacts with RuCl2(CO)3 to give a carbamoyl complex, [)Cl(CO)2], which yields with pyridine (py) and acetylacetone (Hacac), respectively, [)Cl(CO)2(py)] and [)(CO)2(acac)]. These complexes are characterized spectroscopically. The amino group of the ligand is carbonylated and the resulted carbamoyl ligand is chelating through a pyridine ring-N and a carbamoyl-C atom. 2-Aminopyridine and 2-aminopyrimidine react similarly with RuCl2(CO)3 to give the corresponding carbamoyl complexes. |
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