Synthesis of metal paddlanes: X-ray structure determination of bis-(methyl nicotinate)copper(II) acetate dimer |
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| Institution: | 1. Department of Chemistry, Kindai University, 3-4-1 Kowakae, Higashi-Osaka-shi, Osaka 577-8502, Japan;2. Research Institute for Science and Technology, Kindai University, 3-4-1 Kowakae, Higashi-Osaka-shi, Osaka, Japan;1. Faculty of Chemical Engineering and Light Industry, Guangdong University of Technology, Guangzhou 510006, P.R. China;2. MOE Laboratory of Bioinorganic and Synthetic Chemistry, School of Chemistry and Chemical Engineering, Sun Yat-Sen University, Guangzhou 510275, P.R. China |
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| Abstract: | The synthesis of nicotinic acid based N,N′-bidentate ligands capable of spanning the axial sites of copper(II) acetate dimer are reported. Reaction of these ligands with Cu(C2H302)2]2·2H20 gave the 1:1 adduct: a metal paddlane, which on recrystallization from MeOH/CHCl3 yielded the trans-esterified complex Cu(C2H3O2)2]2·2C7H7N02, 3. A single crystal X-ray structure determination of 3 is presented. |
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