Bis(dimethylphosphino)methane complexes of ruthenium carbonyl |
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| Affiliation: | 1. Natural Resources Canada, CanmetENERGY, 1 Haanel Drive, Ottawa K1A 1M1, Canada;2. Department of Chemical and Biological Engineering, University of Ottawa, 161 Louis Pasteur Street, Ottawa K1N 6N5, Canada;3. Environmental Science and Technology Department, Cranfield University College Road, Bedfordshire MK43 0AL, United Kingdom;1. Istituto di Ricerche sulla Combustione, Consiglio Nazionale delle Ricerche, Piazzale Vincenzo Tecchio 80, 80125 Napoli, Italy;2. Dipartimento di Ingegneria Chimica, dei Materiali e della Produzione Industriale, Università degli Studi di Napoli Federico II, Piazzale Vincenzo Tecchio 80, 80125 Napoli, Italy;1. Grupo de Tecnologia Aplicada à Otimização (GTAO)/Universidade Federal do Paraná (UFPR), Brazil;2. Interuniversity Research Centre on Enterprise Networks, Logistics and Transportation (CIRRELT), Canada;3. Faculté des sciences de l''administration, Pavillon Palasis-Prince, 2325, rue de la Terrasse, Université Laval, Québec, Canada;4. Faculté de foresterie, de géographie et de géomatique, Pavillon Abitibi-Price, 2405, rue de la Terrasse, Université Laval, Québec, Canada |
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| Abstract: | Reaction of Me2PCH2PMe2 with [Ru3(CO)12] in a 1:1 or 2:1 ratio in the presence of [(Ph3P)2N]CN catalyst gives [Ru3(CO)10(μ-Me2PCH2PMe2)] and [Ru3(CO)8(μ-Me2PCH2PMe2)2] respectively. The complexes were characterized by elemental analysis, IR and 1H and 31P NMR spectroscopies. |
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