The reactions of nitrogen trichloride with some tertiary phosphines |
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| Affiliation: | 1. Clermont Université, Université d''Auvergne, Unité de Nutrition Humaine, BP 10448, F-63000 Clermont-Ferrand, France;2. INRA, UMR 1019, UNH, CRNH Auvergne, F-63000 Clermont-Ferrand, France;3. Plateforme d''Exploration du Métabolisme, INRA, Centre Clermont-Ferrand–Theix, UMR 1019 , Nutrition Humaine, Saint-Genès-Champanelle, France;1. Department of Radiology and Medical Imaging, University of Virginia, Charlottesville, VA, USA;2. Singapore Institute for Clinical Sciences, Agency for Science, Technology and Research, Singapore;3. Department of Public Health Sciences, University of Virginia, Charlottesville, VA, USA;4. Department of Diagnostic Radiology and Nuclear Medicine, University of Maryland, Baltimore, MD, USA;5. Laboratory of Molecular Imaging, Singapore Bioimaging Consortium, Agency for Science, Technology and Research, Singapore, Singapore;6. Clinical Imaging Research Centre, Agency for Science, Technology and Research, Singapore, NUS-A*STAR, Singapore |
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| Abstract: | Nitrogen trichloride reacts with trimethyl-, triethyl-, tri-n-butyl-, and triphenylphosphine to yield dichlorophosphoranes of the general formula R3PCl2 plus dinitrogen. Nitrogen trichloride reacts with phosphorus trichloride to yield phosphorus pentachloride plus dinitrogen. Chloramine reacts with phosphorus trichloride to yield a mixture of dichlorophosphazene trimer and tetramer. |
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