Isotope effect on the nonradiative decay in mixed amminechromium(III) complexes |
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| Institution: | 1. Center of Excellence BCG for Sustainable Development, College of Innovation and Management, Songkhla Rajabhat University, Songkhla, 90000, Thailand;2. Center of Excellence in Microbial Diversity and Sustainable Utilization, Chiang Mai University, Chiang Mai 50200, Thailand;3. Faculty of Agricultural Technology, Songkhla Rajabhat University, Songkhla 90000, Thailand;4. Institute of Materia Medica, Xinjiang University, Urumqi 830017, People''s Republic of China |
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| Abstract: | Mixed amminechromium(III) complexes of the general formula Cr(NH3)6−nXn]m (X = H2O, SCN−) have been prepared and deuterated in the presence of a base. Phosphorescence decay times have been measured at ca. 77 K and the isotope effect on the nonradiative deactivation is discussed using Kupka's theory. |
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