Squarate complexes of diamine palladium(II) and platinum(II) |
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| Affiliation: | 1. I. Ya. Postovsky Institute of Organic Synthesis, Ural Branch of the Russian Academy of Sciences, 620137, Ekaterinburg, Russian Federation;2. Institute of Chemical Engineering, Ural Federal University, 620002, Ekaterinburg, Russian Federation;3. Ural Research Institute for Phthisiopulmonology, Branch of National Medical Research Center for Phthisiopulmonology and Infection Diseases, 620039, Ekaterinburg, Russian Federation;1. Department of Chemistry, Jadavpur University, Kolkata 700032, India;2. Department of Chemistry, CICECO-Aveiro Institute of Materials, University of Aveiro, 3810-193 Aveiro, Portugal;3. Instituto de Ciencia Molecular, Departamento de Química Inorgánica, Universidad de Valencia, C/José Beltrán, 2, 46980 Paterna, Valencia, Spain;1. A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 119334, Moscow, Russian Federation;2. Peoples Friendship University of Russia (RUDN University), 117198, Moscow, Russian Federation;1. Department of Chemistry and Chemical Biology, University of New Mexico, Albuquerque, NM 87111, USA;2. Advanced Materials Laboratory, Sandia National Laboratories, Albuquerque, NM 87106, USA;3. Department of Chemistry, School of Science and Technology, Nazarbayev University, Astana 010000, Kazakhstan;1. Department of Chemistry, S. A. Esenin Ryazan State University, 390000, Ryazan, Russian Federation;2. I. P. Pavlov Ryazan State Medical University, 390026, Ryazan, Russian Federation;3. Scientific, Educational and Innovation Center for Chemical and Pharmaceutical Technologies, B. N. Yeltsin Ural Federal University, 620002, Ekaterinburg, Russian Federation;4. Moscow Institute of Physics and Technology, 141701, Dolgoprudny, Moscow Region, Russian Federation;5. Department of Chemistry, M. V. Lomonosov Moscow State University, 119991, Moscow, Russian Federation;6. A. N. Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, 119071, Moscow, Russian Federation;1. N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 119991, Moscow, Russian Federation;2. National Research University Higher School of Economics (HSE University), 101000, Moscow, Russian Federation |
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| Abstract: | Reactions of cis-diaminediaqua palladium and platinum dinitrates and of trans-diaminediaqua platinum dinitrate give complexes of the type Pd(tmeda)(OH)(C4O4)Pd(tmeda)(C4O4H) (tmeda = tetramethylethylenediamine) (1), (en)M(C4O4)2M(en) (en = ethylenediamine (M = Pd, Pt) and trans-[Pt- (NH3)2C4O4]n, respectively. The structures of these compounds are discussed on the basis of their spectroscopic data. |
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