Exploring the effect of chain length of bridging ligands in coordination complexes and polymers derived from mixed ligand systems of pyridylnicotinamides and dicarboxylates |
| |
| Authors: | D. Krishna Kumar |
| |
| Affiliation: | Analytical Science Discipline, Central Salt and Marine Chemicals Research Institute (CSIR), G. B. Marg, Bhavnagar 364 002, Gujarat, India |
| |
| Abstract: | The supramolecular structural diversities in mixed ligand systems derived from a series of dicarboxylate anions with varying chain lengths and N-donor exo-bidentate ligand equipped with hydrogen bonding capable amide backbone with Co(II)/Zn(II) metal centers are analyzed. In this context, two complexes namely (Co(L1)2(malonate)(H2O)2} (1a), {Zn(L1)2(malonate)(H2O)2} (1b) and one coordination polymer namely {[Co(μ-L1)(μ-glutarate)(H2O)] · H2O}n (4) (where L1 = N-(4-pyridyl)nicotinamide) have been synthesized and crystallographically characterized. The main aim of this work is to explore the effects of chain lengths of the anionic carboxylate ligands such as malonate, succinate, maleate, and glutarate, in determining the final architecture of coordination compounds based on the mixed ligands. Analyses of the structures revealed that the length of the bridging ligands have prominent effect in the formation of hierarchical structures. |
| |
| Keywords: | Crystal engineering Hydrogen bonding Mixed ligand systems Supramolecular chemistry X-ray crystal structures |
| 本文献已被 ScienceDirect 等数据库收录！ |
|
