Synthesis of cyclopentadienyl ruthenium(II) complexes containing tethered functionalities |
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| Authors: | Wei Lin Janet Leong Lai Yoong Goh Weng Kee Leong |
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| Institution: | a Department of Chemistry, National University of Singapore, 3 Science Drive 3, Singapore 117543, Singapore
b Department of Chemical and Biomolecular Engineering, National University of Singapore, 4 Engineering Drive 4, Singapore 119260, Singapore |
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| Abstract: | The reaction of C5H4(CH2)nX]Tl (1: n = 2, X = NMe2, OMe, CN; n = 3, X = NMe2) with (η6-C6H6)RuCl(μ-Cl)]2, 2, afforded the sandwich compounds {η5-C5H4(CH2)nX}Ru(η6-C6H6)]PF6, 3, and η5-C5H4(CH2)nX]2Ru, 4. Photolytic cleavage of 3 in acetonitrile afforded the tethered products {η5:κN-C5H4(CH2)nX}Ru(CH3CN)2]PF6, 5. |
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| Keywords: | Cyclopentadienyl Ruthenium Tethered functionalities Synthesis |
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