Synthesis of alkynyl(tricarbonyl)rhenium complexes containing a lightly coordinated diamine ligand |
| |
Authors: | Natalie St. Fleur |
| |
Affiliation: | Department of Chemistry, State University of New York at Stony Brook, Stony Brook, NY 11794, USA |
| |
Abstract: | Several alkynyl(tricarbonyl)diaminerhenium complexes were prepared from corresponding halo complexes and silver acetylides. With the diamine N,N′-dimethylpiperazine the compounds were found to be sufficiently stable to allow synthetic transformations on the acetylide ligand as well as purification by chromatography and subsequent substitution of the diamine ligand by stronger ligands such as phenanthrolines or isocyanides. |
| |
Keywords: | Alkynylrhenium complex Diamine rhenium complex Phenanthroline rhenium complex Bis(isocyanide)rhenium complex |
本文献已被 ScienceDirect 等数据库收录! |