Preparation and photophysical studies of copper(I) and ruthenium(II) complexes of 4,4′-bis(3,5-dimethoxyphenyl)-6,6′-dimethyl-2,2′-bipyridine |
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Authors: | Amar Boudebous Catherine E. Housecroft Markus Neuburger Andrea Listorti Francesco Barigelletti |
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Affiliation: | a Department of Chemistry, University of Basel, Spitalstrasse 51, CH4056 Basel, Switzerland b ISOF - CNR, Via Gobetti 101, 40129 Bologna, Italy |
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Abstract: | We report the synthesis of a new ligand, 4,4′-bis(3,5-dimethoxyphenyl)-6,6′-dimethyl-2,2′-bipyridine, optimised for binding to copper(I) and with pendant functionality that can eventually be developed into metallodendritic structures. The synthesis and photophysical properties of complexes with copper(I) and ruthenium(II) are reported. The solid state structure of the complex [Cu(1)2][PF6] · MeCN (1 = 4,4′-bis(3,5-dimethoxyphenyl)-6,6′-dimethyl-2,2′-bipyridine) is also described. |
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Keywords: | 2,2&prime :6&prime ,2&Prime -Terpyridine Ruthenium Copper Photophysics 2,2&prime -Bipyridine |
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