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Platinum(II) and copper(I) 1-(2-diphenylphosphino-1-naphthyl) isoquinoline complexes: Synthesis and phosphorescence at ambient conditions
Authors:Valeri Pawlowski
Institution:Institut für Anorganische Chemie, Universität Regensburg, D-93040 Regensburg, Germany
Abstract:The compounds Pt(quinap)(CN)2, View the MathML source and Cu(quinap)I]2 with quinap = 1-(2-diphenylphosphino-1-naphthyl)isoquinoline were synthesized. Quinap is a bidentate ligand which contains a isoquinoline and an arylphosphine group with CT acceptor properties. Accordingly, the Pt(II) and Cu(I) quinap complexes are characterized by a phosphorescence originating from the lowest-energy MLCT triplets with some IL admixture.
Keywords:Luminescence  Phosphorescence  Platinum(II)  Copper(I)  1-(2-Diphenylphosphino-1-naphthyl)isoquinoline
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