Platinum(II) and copper(I) 1-(2-diphenylphosphino-1-naphthyl) isoquinoline complexes: Synthesis and phosphorescence at ambient conditions |
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Authors: | Valeri Pawlowski |
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Institution: | Institut für Anorganische Chemie, Universität Regensburg, D-93040 Regensburg, Germany |
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Abstract: | The compounds Pt(quinap)(CN)2, and Cu(quinap)I]2 with quinap = 1-(2-diphenylphosphino-1-naphthyl)isoquinoline were synthesized. Quinap is a bidentate ligand which contains a isoquinoline and an arylphosphine group with CT acceptor properties. Accordingly, the Pt(II) and Cu(I) quinap complexes are characterized by a phosphorescence originating from the lowest-energy MLCT triplets with some IL admixture. |
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Keywords: | Luminescence Phosphorescence Platinum(II) Copper(I) 1-(2-Diphenylphosphino-1-naphthyl)isoquinoline |
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