Intramolecular formation and cleavage of C-S/N bonds promoted by iron-sulfur coordination chemistry |
| |
Authors: | Xiufeng Wang Fei Peng Xirui Zeng Xiaoming Liu |
| |
Institution: | a Department of Chemistry/Institute for Advanced Study, Nanchang University, 999 Xue Fu Da Dao, Nanchang 330031, China b School of Chemistry and Chemical Engineering, Jinggangshan University, Jian 343000, China |
| |
Abstract: | The reaction of a tetradentate ligand, 2,2′-(pyridin-2-ylmethylazanediyl)diethanethiol (H2L), with dodecacarbonyltriiron in dry toluene leads to the formations of a hexacarbonyl complex, Fe2(EDT)(CO)6] (EDT = ethylenedithiolate), 1a, which is fully characterised. The formation of this complex is via intramolecular C-S/N bonds formation/cleavage promoted by iron-sulfur coordination chemistry. A possible mechanism for the C-S/N bonds formation/cleavage in the formation of the complex is proposed. |
| |
Keywords: | [FeFe]-hydrogenase Di-iron-carbonyl model complexes Carbon-sulphur/nitrogen bonds formation/cleavage Pyridine derivative Tetradentate ligand |
本文献已被 ScienceDirect 等数据库收录! |
|