Bis(O2S2 macrocycle) complexes of palladium(II) |
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Authors: | So Young Lee |
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Institution: | Department of Chemistry and Research Institute of Natural Science, Gyeongsang National University, Jinju 660-701, South Korea |
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Abstract: | Two isomeric dibenzo-O2S2 macrocycles L1 and L2 have been synthesised and their coordination chemistry towards palladium(II) has been investigated. Two-step approaches via reactions of 1:1-type complexes, cis-Cl2LPd] (1a: L = L1, 1b: L = L2), with different O2S2 macrocycle systems (L1 and L2) have led to the isolation of the following bis(O2S2 macrocycle) palladium(II) complexes in the solid state: Pd(L1)2](ClO4)2 (2a) and a mixture of Pd(L1)2](ClO4)2 (2a) + Pd(L2)2](ClO4)2 (2b). |
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Keywords: | Bis(O2S2 macrocycle) complex Palladium(II) Isomer Crystal structure |
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