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Stereoselective synthesis of cyclometalated iridium(III) complexes: Characterization and photophysical properties |
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| Authors: | Liangru Yang,Alex von Zelewsky,Huong P. Nguyen,Gaë l Labat |
| Affiliation: | a School of Chemistry and Chemical Engineering, He’nan University of Technology, 450001 He’nan, P.R. China b Department of Chemistry, University of Fribourg, Pérolles, 1700 Fribourg, Switzerland c Department of Chemistry, San José State University, One Washington Square, San José, CA 95192-0101, United States d Institute of Microtechnology, University of Neuchâtel, 2002 Neuchâtel, Switzerland |
| Abstract: | The stereoselective synthesis of a highly luminescent neutral Ir(III) complex comprising two bidentate chiral, cyclometalating phenylpyridine derivatives, and one acetylacetonate as ligands is described. The final complex and some intermediates were characterized by X-ray structural analysis, NMR-, CD-, and CPL-spectroscopy. |
| Keywords: | Irdium Cyclometalated complexes Stereoselective synthesis Circular polarized luminescence |
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