Analysis of the main structural trends for biscyclometalated dinuclear rhodium compounds with nitrogen donor axial ligands |
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| Authors: | Julio Esteban |
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| Institution: | Departamento de Química Inorgánica, Universitat de Valencia, Campus de Burjassot, E-46100 Valencia, Spain |
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| Abstract: | A new series of biscyclometalated dinuclear rhodium(II) compounds with the general formula Rh2(O2CR)2(PC)2 · (N)2 have been obtained, where PC is a cyclometalated phosphine, R an aliphatic group, and N a nitrogen donor ligand. The crystal structures for these compounds have been determined by X-ray diffraction. The most important structural trends have been analyzed, and have also been compared with the same parameters for different analogous compounds described previously in the literature. |
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| Keywords: | Rhodium biscyclometalated Nitrogen axial ligands Structural trends X-ray studies NMR |
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