Functionalised dithiocarbamate complexes: Synthesis and molecular structures of bis(2-methoxyethyl)dithiocarbamate complexes [M{S2CN(CH2CH2OMe)2}2] (M = Ni, Cu, Zn) and [Cu{S2CN(CH2CH2OMe)2}2][ClO4] |
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| Authors: | Graeme Hogarth Ebony-Jewel C.-R.C.R. Rainford-Brent Idris Richards |
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| Affiliation: | Department of Chemistry, University College London, 20 Gordon Street, London WC1H OAJ, UK |
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| Abstract: | The bis(2-methoxyethyl)dithiocarbamate complexes [M{S2CN(CH2CH2OMe)2}2] (M = Ni, Cu, Zn, Pd) are readily prepared and the three lighter complexes have been crystallographically characterised. Disproportionation of [Cu{S2CN(CH2CH2OMe)2}2] upon addition of Cu(ClO4)2 · 6H2O affords the copper(III) complex [Cu{S2CN(CH2CH2OMe)2}2][ClO4] which has also been crystallographically characterised. Unlike other copper(III) dithiocarbamate salts, there are no intermolecular cation-cation or cation-anion interactions. |
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| Keywords: | Dithiocarbamate Crystal structures Methoxy Copper(III) |
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