A series of thiolato-bridged di- and trinuclear complexes derived from [Tp∗Rh(SPh)2(MeCN)] (Tp∗ = hydrotris(3,5-dimethylpyrazol-1-yl)borate) |
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| Authors: | Yoshiyuki Misumi |
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| Affiliation: | Institute of Industrial Science, The University of Tokyo, Komaba, Meguro-ku, Tokyo 153-8505, Japan |
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| Abstract: | Treatment of the Rh(III) complex [Tp∗Rh(SPh)2(MeCN)] (1) with a series of late transition metal complexes resulted in the formations of thiolate-bridged di- and trinuclear complexes, which include the Rh(III)-Rh(I) complexes, [Tp∗RhCl(μ-SPh)2Rh(cod)] (2) and [Tp∗RhCl(μ-SPh)2Rh(PPh3)2], the Rh(III)-Pd(II) complexes, [Tp∗RhCl(μ-SPh)2Pd(η3-C3H5)] (4), [{Tp∗Rh(MeCN)}(μ-SPh)2PdCl2] (5), and [{Tp∗RhCl(μ-SPh)2}2Pd] (6), and the Rh(III)-Pt(II) complex [{Tp∗RhCl(μ-SPh)2}2Pt] (7). Early-late transition metal complexes containing the Rh(III)-Re(I) and Rh(III)-Mo(0) metal centers, [Tp∗RhCl(μ-SPh)2Re(CO)4] and [{Tp∗Rh(CO)}(μ-SPh)2Mo(CO)4] were also prepared from 1. The X-ray analysis has been carried out to confirm the structures for 2, 4, 5, 6, and 7. |
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| Keywords: | Multinuclear complex μ-Thiolato complex Hydrotris(pyrazolyl)borato complex X-ray structure Rhodium |
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