The [2+1] Cycloaddition of Singlet Oxycarbonylnitrenes to C60 |
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Authors: | Montserrat Cases Miquel Duran Miquel Solà |
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Institution: | (1) Institut de Química Computacional, Universitat de Girona, E-17071 Girona, Catalonia, Spain. E-mail: miquel@iqc.udg.es, ES |
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Abstract: | Semiempirical and density functional calculations have been carried out to discuss the origin of the closed 5,6]-aza-bridged adduct obtained as a minor product in the reaction of singlet nitrenes with C60. The results indicated that the most likely source is the direct addition of singlet nitrenes to a 5,6]-bond of C60, in contradiction to the common belief that the 5,6]-bonds are not attacked in cycloaddition reactions to C60.Electronic Supplementary Material available. |
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Keywords: | Nitrene additions Buckminsterfullerene C60 NCOOCH3 AM1 B3LYP/6-31G**//AM1 |
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