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Trans-cis amide bond isomerization in fulleroprolines |
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| Authors: | Alberto Bianco Vittorio Lucchini Michele Maggini Maurizio Prato Gianfranco Scorrano Claudio Toniolo |
| Abstract: | The 1H NMR study of fulleroproline derivative Ac-Fpr-OtBu and its Pro analogue Ac-l -Pro-OtBu over a range of temperatures in toluene-d8 solution has enabled the comparison of their equilibrium and activation parameters for the trans/cis interconversion around the amide partial double bond. © 1998 European Peptide Society and John Wiley & Sons, Ltd. |
| Keywords: | trans-cis amide equilibrium dynamic nuclear magnetic resonance fulleroproline NOE differential spectroscopy proline |