Filter materials for phosphorus removal from wastewater in treatment wetlands—A review |
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Authors: | Christina VohlaMargit Kõiv H John BavorFlorent Chazarenc Ülo Mander |
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Institution: | a Department of Geography, Institute of Ecology and Earth Sciences, University of Tartu, 46 Vanemuise St., Tartu 51014, Estonia b Water Research Laboratory, University of Western Sydney-Hawkesbury, Locked Bag 1797, Penrith South DC, NSW 1797, Australia c Ecole des Mines de Nantes, GEPEA UMR CNRS 6144, 4, rue Alfred Kastler, B.P. 20722, F-44307 Nantes Cedex 3, France |
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Abstract: | This paper aims to collect and analyse existing information on different filter media used for phosphorus (P) removal from wastewater in constructed wetlands. The most commonly used materials are categorized as natural materials (considered in 39 papers), industrial byproducts (25 papers) and man-made products (10 papers). A majority of studies on sorbents have been carried out in lab-scale systems as batch experiments, and only very few studies have highlighted results on full-scale systems. Among the great variety of filter media studied, most of materials had a pH level >7 and high Ca (CaO) content. The highest P-removal capacities were reported for various industrial byproducts (up to 420 g P kg−1 for some furnace slags), followed by natural materials (maximum 40 g P kg−1 for heated opoka) and man-made filter media (maximum 12 g P kg−1 for Filtralite). We found a significant positive Spearman Rank Order Correlation between the P retention and CaO and Ca content of filter materials (R2 = 0.51 and 0.43, respectively), whereas the relation of P retention to pH level was weak (R2 = 0.22) but significant. There is probably an optimal level of hydraulic loading rate at which the P removal is the highest. Additional important factors determining the applicability of filter materials in treatment wetlands such as saturation time, availability at a local level, content of heavy metals, and the recyclability of saturated filter media as fertilizer should be taken into consideration. |
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Keywords: | Ash Bauxite Constructed wetlands Freundlich equation Langmuir equation LECA Limestone Peat Saturation Slags |
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