The reaction of polylysine with 2,4-dinitrofluorobenzene. |
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| Authors: | R C Parker R Rakowitz D S Kristol |
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| Affiliation: | 1. Department of Orthopaedics, The Second Affiliated Hospital and Yuying Children’s Hospital of Wenzhou Medical University, Wenzhou, Zhejiang, China;2. The Second School of Medicine, Wenzhou Medical University, Wenzhou, Zhejiang, China;1. Restek Corporation, 110 Benner Circle, Bellefonte, PA 16823, United States;2. Juniata College, 1700 Moore Street, Huntingdon, PA 16652, United States;1. Faculty of Chemistry, University of Mazandaran, Babolsar, 47416-95447, Iran;2. School of Chemistry, Damghan University, Damghan, 36716-41167, Iran;3. School of Engineering, University of British Columbia, Kelowna, BC, V1V 1V7, Canada;4. College of Materials Science and Engineering, Shenzhen Key Laboratory of Polymer Science and Technology, Guangdong Research Center for Interfacial Engineering of Functional Materials, Nanshan District Key Lab. for Biopolymers and Safety Evaluation, Shenzhen University, Shenzhen, 518055, PR China;5. Department of Chemistry, The University of Lahore, Lahore, 54590, Pakistan;6. Center for Micro-BioRobotics, Istituto Italiano di Tecnologia (IIT), Viale R. Piaggio 34, 56025, Pontedera, Pisa, Italy;7. Aix-Marseille University, CNRS, IRD, INRA, Coll France, CEREGE, 13100, Aix en Provence, France;8. Institute of Research and Development, Duy Tan University, Da Nang, 550000, Viet Nam;9. Faculty of Environment and Chemical Engineering, Duy Tan University, Da Nang, 550000, Viet Nam;10. Department of Chemical Engineering, School of Mining, Metallurgy and Chemical Engineering, University of Johannesburg, P. O. Box 17011, Doornfontein, 2028, South Africa;11. Chemical Methods and Treatment Branch, Water Infrastructure Division, Center for Environmental Solutions and Emergency Response, U. S. Environmental Protection Agency, 26 West Martin Luther King Drive, Cincinnati, OH, 45268, USA;12. Regional Center of Advanced Technologies and Materials, Department of Physical Chemistry, Faculty of Science, Palacky University, Š lechtitelů 27, 783 71, Olomouc, Czech Republic;13. International Research Centre of Nanotechnology for Himalayan Sustainability (IRCNHS), Shoolini University, Solan 173212, Himachal Pradesh, India;1. Job Results Management Institute, 2544 Wakewood Hill Court Winston-Salem, NC 27106, U.S.A.;2. Sheldon B. Lubar School of Business, University of Wisconsin, 3202 N. Maryland Avenue Milwaukee, WI 53202, U.S.A.;1. College of Mechanical and Electronic Engineering, Northwest A&F University, Yangling 712100, China;2. School of Mechanical and Power Engineering, Henan Polytechnic University, Jiaozuo 454003, China;3. Key Laboratory of Agricultural Internet of Things, Ministry of Agriculture and Rural Affairs, Yangling 712100, China |
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| Abstract: | - 1.1. Kinetics of the reaction of 2,4-dinitrofluorobenzene with poly-1-lysine has been investigated over the pH range 8.5–10.85.
- 2.2. The reactivity of the polylysine was resolved into four parts; two associated with helical regions and two associated with coil regions.
- 3.3. The helical and coil regions were further resolved into uncatalyzed and hydroxide catalyzed components.
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